The key to frequency and spacing of attachment points for PV is to distribute loads to the metal standing seam panels in a manner that is consistent with the intended distribution of loads from the roof panels into the building structure.
With very few exceptions, the attachment of a single S-5! clamp (even the “Mini”) to the seam will be stronger than a single point of attachment of the seam to the building structure. Hence the “weak link” is not the S-5! clamp, but the attachment clips that hold the metal panels to the building structure, or the beam strength of the roof panel seam, itself.
The most conservative approach to the spacing/frequency of PV attachment to the roof is to determine the spacing/frequency of the roof’s attachment to the building structure; then duplicate it at minimum.
Read more about how to determine panel attachment spacing.